- The relativistic correction to the Hydrogen Hamiltonian is
.
Assume that electrons have spin zero and that there is therefore no
spin orbit correction.
Calculate the energy shifts and draw an energy diagram for the n=3 states
of Hydrogen.
You may use
and
.
- Calculate the fine structure energy shifts (in eV!)
for the , , and states of Hydrogen.
Include the effects of relativistic corrections, the spin-orbit interaction, and the so-called
Darwin term (due to Dirac equation). Do not include hyperfine splitting or
the effects of an external magnetic field. (Note: I am not asking you to derive the
equations.) Clearly list the states in spectroscopic notation and make a diagram showing the
allowed electric dipole decays of these states.
- Calculate and show the splitting of the states (as in the previous problem)
in a weak magnetic field B. Draw a diagram showing the states before and after the
field is applied
- If the general form of the spin-orbit coupling for a particle of
mass and spin moving in a potential is
,
what is the effect of that coupling on the spectrum of an
electron bound in a 3D harmonic oscillator?
Give the energy shifts and and draw a diagram for the and states.

for the , ,

for the , ,

for the , . - We computed that the energies after the fine structure corrections to the hydrogen spectrum are . Now a weak magnetic field is applied to hydrogen atoms in the state. Calculate the energies of all the states (ignoring hyperfine effects). Draw an energy level diagram, showing the quantum numbers of the states and the energy splittings.
- In Hydrogen, the state is split by fine structure corrections into states of definite ,,, and . According to our calculations of the fine structure, the energy only depends on . We label these states in spectroscopic notation: . Draw an energy diagram for the states, labeling each state in spectroscopic notation. Give the energy shift due to the fine structure corrections in units of .
- The energies of photons emitted in the Hydrogen atom
transition between the 3S and the 2P states are measured, first with
no external field, then, with the atoms in a uniform magnetic field B.
Explain in detail the spectrum of photons before and after the field
is applied. Be sure to give an expression for any relevant energy
differences.

Jim Branson 2013-04-22